Ebook Download Active Sites of Polymerization: Multiplicity: Stereospecific and Kinetic Heterogeneity (New Concepts in Polymer Science)From CRC Press
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Active Sites of Polymerization: Multiplicity: Stereospecific and Kinetic Heterogeneity (New Concepts in Polymer Science)From CRC Press
Ebook Download Active Sites of Polymerization: Multiplicity: Stereospecific and Kinetic Heterogeneity (New Concepts in Polymer Science)From CRC Press
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The monograph is intended to systematize data on active sites and their kinetic and stereospecific heterogeneity (polysite phenomenon) in olefin and diene monomer ion, ion-coordination and complex radical polymerization processes. Questions of molecular-mass distribution of polymers obtained by ion and ion-coordination polymerization methods are discussed together with composition and stereo regularity distribution of olefin copolymers. Data on the influence of transition and non-transition metal origin and their ligand ambience, conditions of catalytic system preparation and polymerization are shown. Various assessment methods of polymerization active site distribution by kinetic activity and stereospecific action are considered. In particular, an assessment method for kinetic activity distribution at ion-coordination diene polymerization is described, mathematical simulation parameters for polymerization processes are shown, taking into account the polysite structure of catalytic systems. Of special attention are geometrical and electron structure of active sites in the ion-coordination polymerization by the quantum chemistry method, interrelation between reactivity of some types of active sites and stereospecificity of their action in diene polymerization. The importance of ratio between specific time elementary act duration at the diene injection, coordinated on an active site, and time of propagating macrochain end unit existence in the s-state at polydiene microstructure formation is indicated. Questions of the polysite mechanism occurrence in complex radical polymerization processes are discussed. A possibility for polymerization to proceed in both free-radical and complex related chain propagation sites is shown.
- Published on: 2005-03-28
- Released on: 2005-03-28
- Format: Kindle eBook
Most helpful customer reviews
1 of 1 people found the following review helpful.
Active sites
By Taraky Rodrigues
I have not seen original publications of the authors/editor in the medium- or even in the low impact scientific journals on the subject of the book. It is obviously a compilation of available to them scientific/technical papers. I strongly recommend ignoring this compilation.
0 of 0 people found the following review helpful.
Active sites
By Taraky Rodrigues
I have not seen original publications of the authors in the medium- or even in the low impact scientific journals on the subject of the book. It is obviously a compilation of available to them scientific/technical literature. I strongly recommend ignoring this compilation.
There are approximately 450 books which are authored (co-authored, edited, co-edited) by Zaikov. This is a very impressive number.
An immediate question pops up: What is the quality of such books?
Let anyone make an educated guess.
We will mention only that Zaikov covers the following topics: quantum chemistry, nanochemistry, nanotechnology, organic, inorganic, physical, polymer chemistry, photochemistry, radiation chemistry, organoelemental chemistry, thermodynamics, material science, catalysis, industrial chemistry, food chemistry, and medicinal chemistry. Active research scientist Zaikov is at the cutting edge of almost all of these sciences or subjects.
Interestingly, the Publishers continue to print these superficial compilations and propagate mediocrity.
0 of 0 people found the following review helpful.
Active sites
By Taraky Rodrigues
I have not seen original publications of the authors and of teh editor in the medium- or even in the low impact scientific journals on the subject of the book. It is obviously a compilation of available to them scientific/technical literature. I strongly recommend ignoring this compilation.
(There are approximately 350 books which are authored (co-authored, edited, co-edited) by Zaikov. This is a very impressive number. An immediate question pops up: What is the quality of such books? Let anyone make an educated guess.
We will note only that Renaissance man Zaikov covers all possible chemistry-related topics: quantum chemistry, nanochemistry, nanotechnology, organic, inorganic, physical, polymer chemistry, photochemistry, radiation chemistry, thermodynamics, material science, catalysis, food chemistry, and medicinal chemistry. It is interesting that prolific writer Zaikov is at the cutting edge of almost all of these sciences.)
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